Lives listing with initial: A
- Alexander, Christine (born 1762–died 1845), Scottish home-maker
- Alexander, J. A. (flourished c. 1796), English lawyer
- Alexander, James Wadman (born c. 1767–died 1837), English churchman, university teacher, university administrator
- Alexander, Jane (born 1765–died 1843), Scottish home-maker
- Alexander, John [junior] (born 1762–died 1831), English lawyer, landowner
- Alexander, Major-general William (born 1726–died 1783), American landowner, soldier, army officer
- Alexander, William (born 1729–died 1818), Scottish banker, secret agent, civil servant, spy
- Alexander of Ballochmyle, Claud (born 1753–died 1809), Scottish mill-owner, East India Company official
- Alfano, padre Tommaso Maria (born c. 1680–died 1742), Italian churchman, scholar, historian, philologist
- Alfieri, conte Vittorio (born 1749–died 1803), Italian tragic poet, author
- Alford, Lady Anne [née Corbet] (born c. 1619–died 1693), English gentlewoman
- Alford, John (born 1647–died 1691), English politician, member of Parliament
- Algarotti, conte Bonomo (died 1776), Italian businessman, collector, art critic
- Algarotti, conte Francesco (born 1712–died 1764), Italian author, science-writer, courtier, intellectual
- Aligre, Étienne François d’, marquis d’Aligre (born 1727–died 1798), French magistrate
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