Lives listing by occupation: diplomat
- Durini, Angelo Mario (flourished 1767–1772), Italian churchman, diplomat
- Dutens, Vincent Louis (born 1730–died 1812), French academician, diplomat
- Echeverría, José Tiburcio (died 1822), Colombian politician, diplomat
- Edelsheim, Georg Ludwig von, baron von Edelsheim (born c. 1740–died c. 1814), German aristocrat, diplomat
- Eden, William, 1st Baron Auckland (born 1744–died 1814), English diplomat, prison reformer
- Ehrensvård, Gustaf Johan, Baron Ehrensvård (born 1746–died 1783), Swedish courtier, diplomat
- Elliot, Hugh (born 1752–died 1830), Scottish diplomat, colonial governor
- Elliot Murray Kynynmound, Gilbert, 2nd earl of Minto (born 1782–died 1859), English diplomat, politician, member of Parliament
- Erskine, Thomas, 9th earl of Kellie (born 1745/1746–died 1828), Scottish aristocrat, merchant, diplomat
- Eymar Du Bignosc, Ange Marie d’ (born 1747–died 1803), French civil servant, diplomat, army officer, soldier, revolutionary
- Feriol, Charles Augustin, comte d’Argental (born 1700–died 1788), French aristocrat, diplomat
- Fernandes Tomás, José (born c. 1775), Portuguese diplomat
- Ferrero, Carlo Francesco Vincenzo, marchese d’Ormea (born 1680–died 1745), Italian diplomat, prime minister
- Ferrero de Fiesco, Don Felipe Victorio Amadeo, prince de Masserano (born 1713–died 1777), Spanish aristocrat, diplomat, ambassador
- Finch, Heneage, 3rd earl of Winchilsea (born 1628–died 1689), English aristocrat, diplomat
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