Lives listing by occupation: diplomat
- Broglie, Charles François de, comte de Broglie (born 1719–died 1781), French aristocrat, soldier, military officer, diplomat
- Broglie, François Marie de, 1st duc de Broglie (born 1671–died 1745), French aristocrat, soldier, military officer, diplomat
- Brown, Neil (born 1655–died 1740), English merchant, diplomat
- Brühl zu Martinskirch, Hans Moritz von, graf von Brühl zu Martinskirch (born 1736–died 1809), German diplomat
- Brydges, Sir Harford Jones, 1st baronet (born 1764–died 1847), English diplomat, East India Company official
- Buisson, Pierre de, chevalier de Beauteville (born 1703), French diplomat
- Bulgakov, Yakov Ivanovich (born 1743–died 1809), Russian diplomat
- Burmania, Berthold van (flourished 1741–1762), Dutch diplomat
- Burnett, Alexander, 4th laird of Kemnay (born 1735–died 1802), Scottish diplomat, agriculturalist
- Buschey-Desnoës, Dioulin (flourished 1750–1820), French army officer, diplomat, civil servant, politician
- Bussy, François de (born 1699–died 1780), French diplomat, spy
- Byeloselsky-Byelosersky, Prince Aleksandr Mikhailovich (born 1752–died 1809), Russian aristocrat, courtier, diplomat
- Caillard, Antoine Bernard (born 1737–died 1807), French diplomat
- Cantemir, Antioch, prince of Russia (born 1708–died 1744), Moldavian author, poet, diplomat
- Caracciolo, Domenico, marchese di Villamaina (born 1715–died 1789), Italian diplomat, regional governor
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