Lives listing by occupation: diplomat
- Salignac, Gabriel Jacques de, marquis de La Mothe-Fénelon (born 1688–died 1746), French diplomat, army officer
- Sandoz-Rollin, David Alphonse de (born 1740–died 1809), Swiss diplomat
- Sarotti, Paolo (born 1633–died after 1689), Italian politician, diplomat, scientist, academician
- Scheffer, Greve Ulric (born 1716–died 1799), Swedish army officer, diplomat, prime minister, politician, member of Parliament
- Scheyb, Franz Christoph (born 1704–died 1777), German diplomat, government minister
- Schlezer, Johann Friedrich von (born 1609–died 1673), German diplomat
- Schmid, Georg Ludwig (born 1720–died 1805), Swiss diplomat, politician, legal author
- Schmidt, Johann Friedrich (flourished 1752–1767), German merchant, diplomat
- Ségur, Louis Philippe de, comte de Ségur (born 1753–died 1830), French diplomat, politician, author, poet
- Sellon, Jean François (born 1707–died 1790), Swiss diplomat
- Silva y Álvarez de Toledo, Fernando de, duque de Alba (born 1714–died 1776), Spanish army officer, diplomat, patron
- Simolin, Ivan Matveyevich (born 1720–died 1799), Russian diplomat
- Smirnov, Yakov Ivanovich (born 1759–died 1840), Russian churchman, diplomat
- Smith, John Adams (born 1788–died 1854), American diplomat
- Sohlenthal, Henrik Frederick von, baron von Sohlenthal (born c. 1672–died 1752), Danish diplomat
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