Lives listing by occupation: diplomat
- Roberti, Cardinal Carlo (born 1605–died 1673), Italian churchman, diplomat, regional governor
- Robethon, Jean de (died 1722), French diplomat
- Roques Bouchard, Henri Étienne, marquis de Clausonnette (born 1731–died 1797), French army officer, diplomat
- Rosén von Rosenstein, Nils (born 1752–died 1824), Swedish diplomat, tutor, courtier
- Rothenburg, Friedrich Rudolf von, graf von Rothenburg (born 1711–died 1751), German army officer, diplomat
- Rulhière, Claude Carloman de (born 1735–died 1791), French army officer, diplomat, academician
- Rumyantsev, Count Nikolai Petrovich (born 1754–died 1826), Russian diplomat, government minister, collector
- Rush, Richard (born 1780–died 1859), American lawyer, politician, civil servant, diplomat
- Ruthall, Reverend Doctor Thomas, bishop of Durham (born c. 1468–died 1523), English churchman, civil servant, diplomat, bishop
- Rycaut, Sir Paul (born 1629–died 1700), English diplomat, academician
- Sabatier de Cabre, Honoré Auguste (born 1737–died 1802), French diplomat
- Sade, Jean Baptiste François Joseph de, comte de Sade (born 1702–died 1767), French army officer, diplomat
- Saint-George, Armand Louis de, comte de Marsay (born 1680–died 1762), French diplomat
- Saint Paul, Horace (born 1729–died 1812), English soldier of fortune, army officer, diplomat
- Saladin d’Onex, Jean Louis (born 1701–died 1784), Swiss diplomat, politician
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