Lives listing by occupation: diplomat
- Porten, Sir Stanier (born 1716–died 1789), English government agent, diplomat
- Portocarrero y Funes de Villalpando, Cristóbal Gregorio, V conde de Montijo (born 1692–died 1763), Spanish aristocrat, diplomat, statesman, civil servant
- Pougens, Marie Charles Joseph de, chevalier de Pougens (born 1755–died 1833), French diplomat, publisher
- Prior, Matthew (born 1664–died 1721), English author, poet, diplomat, politician, member of Parliament, academician
- Prozor, Count Moritz (born 1849–died 1928), Lithuanian aristocrat, diplomat, translator
- Puchot, Rolland, comte Des Alleurs (born 1693–died 1754), French diplomat, author
- Radix de Sainte-Foy, Claude Pierre Maximilien (born 1736–died 1810), French civil servant, diplomat
- Raigersfeld, Johann Lukas von, baron von Raigersfeld (died 1819), Austrian diplomat
- Randolph, Edward (born 1632–died 1703), American diplomat, colonial administrator, civil servant
- Randolph, “of Roanoke”, John (born 1773–died 1833), American plantation-owner, politician, diplomat
- Räsfeld, Johann Peter von (flourished c. 1740), German diplomat
- Rehausen, Gotthard Mauritz von (born 1761–died 1822), Swedish diplomat
- Reybaz, Étienne Salomon (born 1737–died 1804), Swiss diplomat
- Rinhuber, Laurent (died c. 1685), German physician, diplomat, traveller, courtier, interpreter, religious convert, Catholic
- Rivadavia, Bernardino (born 1780–died 1845), Argentinian merchant, militia officer, revolutionary, civil servant, diplomat
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