Lives listing by occupation: diplomat
- Barberie, Dominique Jacques, marquis de Courteille (born 1696–died 1767), French aristocrat, diplomat
- Barberie, François Dominique, marquis de Saint-Contest (born 1701–died 1754), French diplomat, government minister
- Barberini, Cardinal Francesco (born 1597–died 1679), Italian churchman, regional governor, diplomat
- Barbon Mancini-Mazarini, Louis Jules, duc de Nivernais (born 1716–died 1798), French diplomat, patron
- Barlow, Joel (born 1754–died 1812), American businessman, diplomat, poet
- Barrett, Nathaniel (born 1765–died 1853), American merchant, diplomat
- Barrio, José María del (flourished 1820–1830), Guatemalan diplomat
- Barthès de Marmorières, Antoine (born 1736–died 1811), Swiss diplomat, army officer
- Bastiani, Giovanni Battista (born 1714–died 1786), Italian churchman, soldier, courtier, army officer, diplomat
- Beckwith, George (born 1753–died 1823), English army officer, soldier, envoy, diplomat
- Bekhteyev, Fedor Dmitrievich (flourished c. 1757), Russian diplomat
- Berckel, Franco Petrus van (born 1760–died 1836), Dutch diplomat, ambassador
- Berckel, Pieter Johan van (born 1725–died 1800), Dutch politician, diplomat, ambassador
- Berkeley, Charles, 2nd earl of Berkeley (born c. 1649–died 1710), English aristocrat, academician, envoy, East India Company official, politician, member of Parliament, diplomat
- Berkenroode, Mattheus Lestevenon van (born 1715–died 1797), Dutch diplomat
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