Lives listing by occupation: diplomat
- Jay, John (born 1745–died 1829), American founding father, politician, diplomat, lawyer, judge, chief justice
- Kaunitz-Rietberg, Reichsfürst Wenzel Anton von (born 1711–died 1794), Austrian lawyer, diplomat, governor, politician
- Keith, George, 10th Earl Marischal (born 1692/1693–died 1778), Scottish army officer, diplomat
- Keith, Robert (born c. 1697–died 1774), Scottish diplomat, ambassador
- Keith, Lieutenant-general Sir Robert Murray (born 1730–died 1795), Scottish soldier, military officer, diplomat
- Keppel, Lieutenant-general William Anne van, 2nd earl of Albemarle (born 1702–died 1754), English army officer, diplomat, colonial governor
- King, Rufus (born 1755–died 1827), American politician, diplomat
- Knox, William (born 1732–died 1810), American government official, pamphleteer, diplomat
- Koch, Konrad Reinhard von (flourished c. 1774), German diplomat
- Kretschmar, Friedrich (flourished 1657–1676), German physician, alchemist, chemist, diplomat, courtier
- Labat, Jean Louis, baron de Grandcour (died c. 1798), Swiss diplomat, financier
- La Bonde, Charles François de, marquis d’Iberville (born 1653–died 1723), French diplomat
- La Porte Du Theil, Jean Gabriel (born 1683–died 1755), French diplomat
- Larrey, Thomas Isaac de, comte du Saint Empire (born 1703–died 1795), German aristocrat, courtier, diplomat
- La Touche, Charles Nicolas de, chevalier de La Touche (flourished 1751–1756), French military officer, diplomat, army officer
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